This item is not available in game.
To clarify, this item has never been available to players. The concept of a Demon Hunter class in World of Warcraft was originally conceived around Burning Crusade. (My memory is fuzzy, so anyone who can give a more accurate timeframe is welcome.) However, it has never been officially or semi-officially recognized as a possibility; it was/is fairly popular with players and most likely originated from forums.
If you want to see the item in-game, Dizzy One-Eye in Booty Bay is wearing it. There are other NPCs that wear a red blindfold, too.
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